nav emailalert searchbtn searchbox tablepage yinyongbenwen piczone journalimg journalInfo journalinfonormal searchdiv searchzone qikanlogo popupnotification paper paperNew
2025, 24, v.53 16-20
矿区土壤重金属污染评价与生态修复技术研究进展
基金项目(Foundation): 国家重点研发计划项目(2019YFC1803800)
邮箱(Email):
DOI:
摘要:

土壤重金属污染具有易累积、易隐蔽、毒性强、难降解、形态多样且理化性质复杂等特点,不仅破坏土壤结构和生态系统,还会在土壤中长期累积,严重污染土壤、地表水和地下水资源,进而影响农业生产、区域生态安全和人体健康。系统总结了矿区土壤重金属污染现状、评价方法和生态修复技术等方面的研究进展,以期为矿区土壤重金属污染风险防治与生态修复提供科学依据。

Abstract:

The pollution of heavy metals in soil has the characteristics of easy accumulation, easy concealment, strong toxicity, difficult degradation, diverse forms, and complex physical and chemical properties.It not only damages soil structure and ecosystems, but also accumulates in soil for a long time, seriously polluting soil, surface water, and groundwater resources, affecting agricultural production, regional ecological security, and human health.This article systematically summarizes the research progress on the current status, evaluation methods, and ecological restoration technologies of heavy metal pollution in mining soil, providing scientific basis for the risk prevention and ecological restoration of heavy metal pollution in mineral soil.

参考文献

[1] WANG L,JI B,HU Y H,et al.A review on in situ phytoremediation of mine tailings[J].Chemosphere,2017,184:594-600.

[2] 李振涛,付士根,郭利,等.卫星遥感影像在尾矿库安全风险监测中的应用研究[J].中国安全生产科学技术,2025,21(3):126-132.

[3] 毛文权,朱永恒,王海燕,等.铜尾矿复垦地的生态恢复程度与土壤动物指示作用研究[J].安徽农业科学,2020,48(15):71-74.

[4] 尹琛,白丽梅,李绍英,等.铁尾矿综合利用研究进展[J].矿产保护与利用,2023,43(6):41-53.

[5] SUN R G,GAO Y,YANG Y.Leaching of heavy metals from lead-zinc mine tailings and the subsequent migration and transformation characteristics in paddy soil[J].Chemosphere,2022,291:132792.

[6] WANG P,SUN Z H,HU Y A,et al.Leaching of heavy metals from abandoned mine tailings brought by precipitation and the associated environmental impact[J].Science of the total environmen,2019,695:133893.

[7] 付搏涛,李钢,张红,等.基于GDEM-PDyna的尾矿库溃坝三维数值模拟分析研究[J].中国安全生产科学技术,2023,19(2):71-77.

[8] CHEN D,WANG X H,LUO X M,et al.Delineating and identifying risk zones of soil heavy metal pollution in an industrialized region using machine learning[J].Environmental pollution,2023,318:120932.

[9] STEFANOWICZ A M,KAPUSTA P,ZUBEK S,et al.Soil organic matter prevails over heavy metal pollution and vegetation as a factor shaping soil microbial communities at historical Zn-Pb mining sites[J].Chemosphere,2020,240:124922.

[10] TSAI M S,CHEN M H,LIN C C,et al.Children’s environmental health based on birth cohort studies of Asia (2)-air pollution,pesticides,and heavy metals[J].Environmental research,2019,179(Pt A):108754.

[11] 王玲,刘建欣,束浩杰,等.河北某铅锌尾矿库周边土壤重金属元素空间分布及风险评价[J].金属矿山,2025(3):253-261.

[12] 汪楠楠,王宇帆,黄飞,等.铜尾矿库周边农田土壤重金属污染状况及其对大豆生长的影响[J].土壤通报,2024,55(5):1462-1469.

[13] 惠勇,张凤美,王友保,等.铜陵市凤凰山尾矿区重金属污染研究[J].安徽农业科学,2011,39(23):14268-14269.

[14] 杨帆,杨熙斌,黄小凤,等.卡房锡尾矿库重金属污染特征及生态风险评价[J].环境科学,2024,45(12):7177-7186.

[15] 郭学辉,黄仁亮,万建华.冀北山区某有色多金属尾矿库周边农用地重金属污染特征与生态健康风险评价[J].地学前缘,2024,31(2):77-92.

[16] TEPANOSYAN G,SAHAKYAN L,BELYAEVA O,et al.Continuous impact of mining activities on soil heavy metals levels and human health[J].Science of the total environment,2018,639:900-909.

[17] WEI J X,GAO J Q,CEN K.Levels of eight heavy metals and health risk assessment considering food consumption by China’s residents based on the 5th China total diet study[J].Science of the total environment,2019,689:1141-1148.

[18] SΦNDERGAARD J,MOSBECH A.Mining pollution in Greenland-the lesson learned:A review of 50 years of environmental studies and monitoring[J].Science of the total environment,2022,812:152373.

[19] 李家莹,陈亚婷,安燕飞,等.亳州市涡北煤矿周边农田土壤重金属污染评价及来源解析[J].安徽农业大学学报,2021,48(4):641-647.

[20] 王棣,李杰飞,杨浩,等.洛阳市栾川县矿区周边土壤重金属污染特征、来源与生态风险评价[J].环境化学,2024,43(10):3363-3376.

[21] ABRAHAM J,DOWLING K,FLORENTINE S.Assessment of potentially toxic metal contamination in the soils of a legacy mine site in Central Victoria,Australia[J].Chemosphere,2018,192:122-132.

[22] SANTOS DE SOUZA E,TEXEIRA R A,DA COSTA H S C,et al.Assessment of risk to human health from simultaneous exposure to multiple contaminants in an artisanal gold mine in Serra Pelada,Pará,Brazil[J].Science of the total environment,2017,576:683-695.

[23] BARKETT M O,AKüN E.Heavy metal contents of contaminated soils and ecological risk assessment in abandoned copper mine harbor in Yedidalga,Northern Cyprus[J].Environmental earth sciences,2018,77(10):378.

[24] 施建飞,靳正忠,周智彬,等.额尔齐斯河流域典型尾矿库区周边土壤重金属污染评价[J].生态环境学报,2022,31(5):1015-1023.

[25] 张超,贺峰,王姊煜,等.秦岭典型钼矿区农田土壤和作物重金属污染特征、来源解析及健康风险评价[J].环境科学,2024,45(9):5526-5537.

[26] ZHANG C,WANG X,JIANG S H,et al.Heavy metal pollution caused by cyanide gold leaching:A case study of gold tailings in Central China[J].Environmental science and pollution research,2021,28(23):29231-29240.

[27] 于旦洋,王颜红,丁茯,等.近十年来我国土壤重金属污染源解析方法比较[J].土壤通报,2021,52(4):1000-1008.

[28] 李娇,吴劲,蒋进元,等.近十年土壤污染物源解析研究综述[J].土壤通报,2018,49(1):232-242.

[29] FEI X F,LOU Z H,XIAO R,et al.Contamination assessment and source apportionment of heavy metals in agricultural soil through the synthesis of PMF and GeogDetector models[J].Science of the total environment,2020,747:141293.

[30] 陈雅丽,翁莉萍,马杰,等.近十年中国土壤重金属污染源解析研究进展[J].农业环境科学学报,2019,38(10):2219-2238.

[31] CHEN L,ZHOU S L,WU S H,et al.Combining emission inventory and isotope ratio analyses for quantitative source apportionment of heavy metals in agricultural soil[J].Chemosphere,2018,204:140-147.

[32] PENG H,CHEN Y L,WENG L P,et al.Comparisons of heavy metal input inventory in agricultural soils in North and South China:A review[J].Science of the total environment,2019,660:776-786.

[33] GUO X Q,LI S,ZHANG Y M,et al.Applications of dynamic simulation for source analysis of soil pollutants based on atmospheric diffusion and deposition model[J].Science of the total environment,2022,839:156057.

[34] GUAN Q Y,ZHAO R,PAN N H,et al.Source apportionment of heavy metals in farmland soil of Wuwei,China:Comparison of three receptor models[J].Journal of cleaner production,2019,237:117792.

[35] 李雯香,秦培智,唐晗.化学质量平衡法在污染源解析中的应用研究[J].绿色科技,2019,21(14):201-202,204.

[36] 熊才熠.赣南钨矿区土壤重金属污染特征及风险评价[D].南昌:南昌大学,2022.

[37] JIN G Q,FANG W,SHAFI M,et al.Source apportionment of heavy metals in farmland soil with application of APCS-MLR model:A pilot study for restoration of farmland in Shaoxing City Zhejiang,China[J].Ecotoxicology and environmental safety,2019,184:109495.

[38] JIA Z Y,WANG J X,ZHOU X D,et al.Identification of the sources and influencing factors of potentially toxic elements accumulation in the soil from a typical karst region in Guangxi,Southwest China[J].Environmental pollution,2020,256:113505.

[39] HENRY R C.Multivariate receptor modeling by N-dimensional edge detection[J].Chemometrics and intelligent laboratory systems,2003,65(2):179-189.

[40] 张军,董洁,梁青芳,等.宝鸡市区土壤重金属污染影响因子探测及其源解析[J].环境科学,2019,40(8):3774-3784.

[41] LI Y H,KUANG H F,HU C H,et al.Source apportionment of heavy metal pollution in agricultural soils around the Poyang Lake Region using UNMIX model[J].Sustainability,2021,13(9):5272.

[42] ZHOU H,CHEN Y,YUE X M,et al.Identification and hazard analysis of heavy metal sources in agricultural soils in ancient mining areas:A quantitative method based on the receptor model and risk assessment[J].Journal of hazardous materials,2023,445:130528.

[43] HUA C Y,ZHUO H M,KANG A L,et al.Contamination,risk assessment and source apportionment of the heavy metals in the soils of apple orchard in Qixia City,Shandong Province,China[J].Stochastic environmental research and risk assessment,2022,36(9):2581-2595.

[44] 封凯.污染场地周边土壤重金属特征源解析及风险预测方法[D].西安:长安大学,2022.

[45] 毕永顺,朱勇兵,刘祖文,等.基于APCS-MLR受体模型的弹药销毁场土壤重金属源解析[J].环境化学,2024,43(7):2313-2324.

[46] WANG J,SU J W,LI Z G,et al.Source apportionment of heavy metal and their health risks in soil-dustfall-plant system nearby a typical non-ferrous metal mining area of Tongling,Eastern China[J].Environmental pollutiont,2019,254:113089.

[47] 李有文,王晶,巨天珍,等.白银市不同功能区土壤重金属污染特征及其健康风险评价[J].生态学杂志,2017,36(5):1408-1418.

[48] ZHANG T,WANG M G,BAI G L,et al.Distribution characteristics,risk assessment,and source analysis of heavy metals in surface sediments and near-lakeshore soils of a plateau lake in China[J].Gondwana research,2023,115:191-200.

[49] WEI M C,PAN A F,MA R Y,et al.Distribution characteristics,source analysis and health risk assessment of heavy metals in farmland soil in Shiquan County,Shaanxi Province[J].Process safety and environmental protection,2023,171:225-237.

[50] 李军,李旭,李开明,等.基于特定源-风险评估模型的兰州黄河风情线绿地土壤重金属污染优先控制源分析[J].环境科学,2024,45(4):2428-2439.

[51] MOHAMMADI A A,ZAREI A,ESMAEILZADEH M,et al.Assessment of heavy metal pollution and human health risks assessment in soils around an industrial zone in neyshabur,Iran[J].Biological trace element research,2020,195(1):343-352.

[52] LONG Z J,ZHU H,BING H J,et al.Contamination,sources and health risk of heavy metals in soil and dust from different functional areas in an industrial city of Panzhihua City,Southwest China[J].Journal of hazardous materials,2021,420:126638.

[53] 张淑珂,孙国新,姜杰,等.白城市黑土区农田土壤重金属来源解析及积累评价[J].环境科学学报,2023,43(5):409-420.

[54] TAN C,WANG H,YANG Q C,et al.An integrated approach for quantifying source apportionment and source-oriented health risk of heavy metals in soils near an old industrial area[J].Environmental pollution,2023,323:121271.

[55] HAN Q,WANG M Y,XU X H,et al.Health risk assessment of heavy metals in road dust from the fourth-tier industrial city in Central China based on Monte Carlo simulation and bioaccessibility[J].Ecotoxicology and environmental safety,2023,252:114627.

[56] HAKANSON L.An ecological risk index for aquatic pollution control.a sedimentological approach[J].Water research,1980,14(8):975-1001.

[57] GUO B,LIU N,SUI H Z.Analysis on spatial pattern changes of land resources utilization and soil pollution sources in the new period[J].IOP conference series:Earth and environmental science 2020,514(3):032012.

[58] 杨振宇,廖超林,邹炎,等.湘东北典型河源区土壤重金属分布特征、来源解析及潜在生态风险评价[J].环境科学,2023,44(9):5288-5298.

[59] HU Y A,HE K L,SUN Z H,et al.Quantitative source apportionment of heavy metal(loid)s in the agricultural soils of an industrializing region and associated model uncertainty[J].Journal of hazardous materials,2020,391:122244.

[60] FEI X F,LOU Z H,XIAO R,et al.Source analysis and source-oriented risk assessment of heavy metal pollution in agricultural soils of different cultivated land qualities[J].Journal of cleaner production,2022,341:130942.

[61] 胡兆鑫,吴泽燕,罗为群,等.典型岩溶县土壤重金属含量、来源及生态风险评价[J].环境科学,2024,45(9):5506-5516.

[62] 王泓博,苟文贤,吴玉清,等.重金属污染土壤修复研究进展:原理与技术[J].生态学杂志,2021,40(8):2277-2288.

[63] 刘洁,孙可,韩兰芳.生物炭对土壤重金属形态及生物有效性影响的研究进展[J].环境化学,2021,40(6):1643-1658.

[64] SALJNIKOV E,MRVI■,et al.Pollution indices and sources appointment of heavy metal pollution of agricultural soils near the thermal power plant[J].Environmental geochemistry and health,2019,41(5):2265-2279.

[65] 孙涛,徐皓普,于致伟,等.某铅锌冶炼厂周边土壤重金属污染特征研究[J].山东化工,2019,48(17):221-223.

[66] PURAKAYASTHA T J,CHHONKAR P K.Phytoremediation of heavy metal contaminated soils[M]//Soil heavy metals.Berlin,Heidelberg:Springer,2009:389-429.

[67] 周聪.镉污染土壤原位修复技术的研究进展[J].有色冶金设计与研究,2018,39(5):20-24,28.

[68] 张富运.铅锌尾矿库耐性植物的筛选及其耐性机理初步研究[D].长沙:中南林业科技大学,2014.

[69] 丁自立,李书谦,周旭,等.植物修复土壤重金属污染机制与应用研究[J].湖北农业科学,2014,53(23):5617-5623.

[70] 杨金香,李小龙.不同复垦类型木本植物重金属吸收积累差异[J].安徽理工大学学报(自然科学版),2012,32(3):33-36.

[71] 路畅,王英辉,杨进文.广西铅锌矿区土壤重金属污染及优势植物筛选[J].土壤通报,2010,41(6):1471-1475.

[72] 蒋旭光,段茵,吕国钧,等.垃圾焚烧飞灰中重金属固化稳定机理及系统评价方法的研究进展[J].环境工程学报,2022,16(1):10-19.

[73] GOUGAR M L D,SCHEETZ B E,ROY D M.Ettringite and C-S-H Portland cement phases for waste ion immobilization:A review[J].Waste managemen,1996,16(4):295-303.

[74] 王彩萍.水泥对生活垃圾焚烧飞灰的固化作用与Pb、Cd的浸出机理研究[D].武汉:武汉理工大学,2016.

[75] 胡洋.水泥基材料固化/稳定化处理生活垃圾焚烧飞灰重金属及机理研究[D].上海:华东理工大学,2021.

[76] 雒云龙,母维宏,周新涛,等.磷酸镁水泥固化/稳定化重金属性能及作用机理研究进展[J].环境化学,2021,40(12):3875-3886.

[77] MAKUL N,AGRAWAL D K,CHATVEERA B.Microstructures and mechanical properties of portland cement at an early age when subjected to microwave accelerated-curing [J].Journal of ceramic processing research,2011,12(1):62-69.

[78] LOMBARDI F,MANGIAL ARDI T,PIGA L,et al.Mechanical and leaching properties of cement solidified hospital solid waste incinerator fly ash [J].Waste management,1998,18(2):99-106.

[79] LIU Q,WANG X N,GAO M,et al.Heavy metal leaching behaviour and long-term environmental risk assessment of cement-solidified municipal solid waste incineration fly ash in sanitary landfill[J].Chemosphere,2022,300:134571.

[80] SOBIECKA E,OBRANIAK A,ANTIZAR-LADISLAO B.Influence of mixture ratio and pH to solidification/stabilization process of hospital solid waste incineration ash in Portland cement[J].Chemosphere,2014,111:18-23.

[81] AL-KINDI G.Evaluation the solidification/stabilization of heavy metals by Portland cement[J].Journal of ecological engineering,2019,20(3):91-100.

[82] 李丽华,岳雨薇,李文涛,等.固化重金属污染土电阻率与强度特性试验研究[J].武汉大学学报(工学版),2024,57(9):1241-1250.

[83] 陈汉江,崔素丽,张登飞,等.水泥固化锌污染黄土力学特性试验研究[J].西北大学学报(自然科学版),2024,54(1):33-41.

[84] XU J H,FLEITER T,EICHHAMMER W,et al.Energy consumption and CO2 emissions in China’s cement industry:A perspective from LMDI decomposition analysis[J].Energy policy,2012,50:821-832.

[85] SOUSA V,BOGAS J A,REAL S,et al.Industrial production of recycled cement:Energy consumption and carbon dioxide emission estimation[J].Environmental science and pollution research,2023,30(4):8778-8789.

[86] SOUSA V,BOGAS J A,REAL S,et al.Recycled cement production energy consumption optimization[J].Sustainable chemistry and pharmacy,2023,32:101010.

[87] XU D L,CUI Y S,LI H,et al.On the future of Chinese cement industry[J].Cement and concrete research,2015,78:2-13.

[88] SHEN W G,LIU Y,YAN B L,et al.Cement industry of China:Driving force,environment impact and sustainable development[J].Renew sustain energy reviews,2017,75:618-628.

[89] PENIDO E S,MARTINS G C,MENDES T B M,et al.Combining biochar and sewage sludge for immobilization of heavy metals in mining soils[J].Ecotoxicology and environmental safety,2019,172:326-333.

[90] ZHU J F,GAO W C,ZHAO W T,et al.Wood vinegar enhances humic acid-based remediation material to solidify Pb(II) for metal-contaminated soil[J].Environmental science and pollution research,2021,28(10):12648-12658.

[91] 李敏,张然然,田冰雪.无机材料固化镉铅镍污染土的环境效应及失稳机制[J].土木与环境工程学报(中英文),2024,46(4):202-210.

[92] 罗忠涛,肖宇领,杨久俊,等.垃圾焚烧飞灰有毒重金属固化稳定技术研究综述[J].环境污染与防治,2012,34(8):58-62,68.

[93] 朱子晗,陈卫华,华银锋,等.垃圾焚烧飞灰重金属药剂稳定化研究进展[J].化工进展,2021,40(11):6358-6368.

[94] 李建陶,曾鸣,杜兵,等.垃圾焚烧飞灰药剂稳定化矿物学特性[J].中国环境科学,2017,37(11):4188-4194.

基本信息:

中图分类号:X171.4;X53

引用信息:

[1]刘洋,王道涵.矿区土壤重金属污染评价与生态修复技术研究进展[J].安徽农业科学,2025,53(24):16-20.

基金信息:

国家重点研发计划项目(2019YFC1803800)

检 索 高级检索

引用

GB/T 7714-2015 格式引文
MLA格式引文
APA格式引文