陈树科;沈晓飞;江锦花;

• 1:台州学院生命科学学院

摘要(Abstract)：

使用气相色谱-质谱-化学离子源(GC-MS-NCI)检测法对持久性有机污染物多溴联苯醚(PBDEs)的10种同系物(10PBDEs)在海洋鱼类(红鲈、黑鲷、鲈鱼)中的含量进行了检测。结果表明,红鲈、黑鲷、鲈鱼肌肉中10PBDEs的含量分别为252.6～662.2、454.6～1 413.4、147.4～760.5 ng/kg湿重(ww)。鱼肌肉样品中BDE47的相对含量最高。鱼肝对多溴联苯醚的富集能力强于鱼肉。

关键词(KeyWords)： 多溴联苯醚;海洋鱼类;BDE47

Abstract:

Keywords:

基金项目(Foundation): 浙江省温岭市科技项目(2007-35)资助

作者(Author): 陈树科;沈晓飞;江锦花;

Email:

DOI: 10.13989/j.cnki.0517-6611.2009.23.143

参考文献(References)：

• [1]刘汉霞,张庆华,江桂斌.多溴联苯醚及其环境问题[J].化学进展,2005,17(3):554-562.
• [2]RAHMANF,LANGFORD KH,SCRIMSHAWMD,et al.Polybrominateddiphenyl ether(PBDE)flame retardants[J].Science of the Total Environ-ment,2001,275(1/3):1-17.
• [3]AKUTSU K,KITAGAWA M,NAKAZAWA H,et al.Time-trend(1973-2000)of polybrominated diphenyl ethers in Japanese mother’s milk[J].Chemosphere,2003,53:645-654.
• [4]HITES R A.Polybrominated diphenyl ethers in the environment and inpeople:a meta-analysis of concentrations[J].Environmental Science andTechnology,2004,38:945-956.
• [5]DEWITC.An overviewof brominated flame retardants in the environment[J].Chemosphere,2002,46(5):583-624.
• [6]GOUINT,HARNERT.Modellingthe environmental fate of the polybromi-nated diphenyl ethers[J].Environment International,2003,29(6):17-724.
• [7]WATANABE I,TATSUKAWA R.Anthropogenic brominated aromatics inthe Japanese environment:swedish national chemicals inspectorate:pro-ceedings of the workshop on brominated aromatic flame retardants[C].Sweden:Solna,1990.
• [8]BRANCHI I,CAPONE F,VITALONE A,et al.Early developmental expo-sure to bde99 or aroclor1254 affects neurobehavioural profile:interferencefromthe administration route[J].Neuro Toxicology,2005,26(2):183-192.
• [9]DARNERUD P O,RISBERG S.Tissue localisation of tetra-and pentabro-modiphenyl ether congeners(BDE-47,-85,and-99)in perinatal and adultC57BLmice[J].Chemosphere,2006,62(3):485-493.
• [10]DARNERUD P O,WONGJ,BERGMANA,et al.Common viral infectionaffects pentabrominated diphenyl ether(PBDE)distribution and metabolicand hormonal activities in mice[J].Toxicology,2005,210(2/3):159-167.
• [11]向彩红.珠江河口水生生物中多溴联苯醚的初步研究[D].北京:中国科学院研究生院,2006:27-55.
• [12]AKUTSUK,OBANAH,OKIHASHI M,etal.GC/MSanalysis of polybro-minated diphenyl ethers in fish collected fromthe Inland Sea of Seto,Ja-pan[J].Chemosphere 2001,44:1325-1333.
• [13]UENOD,KAJIWARAN,TANAKAH,et al.Global pollution monitoringof polybrominated diphenyl ethers using Skipjack Tuna as a bioindicator[J].Environmental Science and Technology,2004,38:2312-2316.
• [14]VOORSPOELS S,COVACI A,SCHEPENS P.Polybrominated diphenyl e-thers in marine species from the Belgian North Sea and the WesternScheldt Estuary:levels,profiles,and distribution[J].Environmental Sci-ence and Technology,2003,37:4348-4357.
• [15]DE BOER J,WESTER P G,DE HORSTA V,et al.Polybrominated di-phenyl ethersininfluents,suspended particulate matter,sediments.sewagetreatment plantand effluents and biota fromthe Netherlands[J].Environ-mental Pollution,2002,122,63-74.
• [16]BOONJ P,LEWISWE,T,JOEN-A-CHOYMR,etal.Levels of polybro-minated diphenyl ether(PBDE)flame retardants in animals representingdifferent trophic levels of the North Sea food web[J].Environmental Sci-ence and Technology,2002,36:4025-4032.
• [17]IKONOMOUMG,RAYNE S,FISCHER M,et al.Occurrence and conge-ner profiles of polybrominated diphenyl ether(PBDE)in environmentalsample from coastal British Columbia,Canada[J].Chemosphere,2002,46:649-663.
• [18]HITES R A,FORAN J A,SCHWAGER S J,et al.Global assessment ofpolybrominated diphenyl ethers in farmed and wild salmon[J].Environ-mental Science and Technology,2004,38(19):4945-4949.
• [19]CHRISTENSENJ H,GLASIUS M,PECSELI M,et al.Polybrominated di-phenyl ethers(PBDEs)in marine fish and blue mussels from southernGreenland[J].Chemosphere 2002,47:631-638.
• [20]BROWNF R,WINKLER J,VISITA P,et al.Levels of PBDEs,PCDDs,PCDFs,and coplanar PCBs in edible fish from California coastal waters[J].Chemosphere,2006,64:276-286.
• [21]HOLDENA,SHE J,TANNER M,et al.PBDEs in the San Francisco BayArea:measurementsinfish[J].OrganohalogenCompound,2003,61:255-258.
• [22]BURREAUS,ZEBUHR Y,ISHAQR,et al.Comparison of biomagnifica-tion of PBDEs in food chains fromthe Baltic Sea and the Northern Atlan-tic Sea[J].Organohalogen Compound,2000,47:253-255.
• [23]丘耀文,张干,郭玲利,等.大亚湾海域多溴联苯醚的生物累积特征[J].中国环境科学,2006,26(6):685-688.
• [24]WUJ P,LUO X J,ZHANG Y,et al.Bioaccumulation of polybrominateddiphenyl ethers(PBDEs)and polychlorinated biphenyls(PCBs)in wild a-quatic species from an electronic waste(e-waste)recycling site in SouthChina[J].Environment Internatinal,2008,34:1109-1113.
• [25]林竹光,张莉莉,孙若男,等.动物肝脏中九种多溴联苯醚残留量的GC-NCI/MS分析[J].分析试验室,2008,27(7):30-34.
• [26]郭英,唐洪磊,孟祥周,等.多溴联苯醚在桂花鱼体内的分布[J].环境科学,2007,28(12):2806-2810.
• [27]BURREAUS,BROMAND,ORNU.Tissue distribution of 2,2′,4,4′-tet-rabromo[14C]diphenyl ether([14C]-PBDE47)in pike(Esox lucius)afterdietary exposure-a time series study using whole body autoradiography[J].Chemosphere,2000,40:977-985.
• [28]向彩红,罗孝俊,余梅,等.珠江河口水生生物中多溴联苯醚的分布[J].环境科学,2006,27(9):1732-1737.
• [29]吕杨,王立宁,黄俊,等.海河渤海湾地区沉积物、鱼体样品中多溴联苯醚的水平与分布[J].环境污染与防治,2007,29(9):652-660.